Technion - Israel Institute of Technology Schulich Faculty of Chemistry

Ph.D. Thesis:

Enantioselective and Diastereoselective Synthesis of Functionalized Allenes
(Ilan Marek, 1988)

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Papers:

133) Rozalia Unger, Theodore Cohen, Ilan Marek*
Tandem Zn-Brook rearrangement/Ene-Allene Carbocyclization
Eur. J. Org. Chem. (2009), in press

132) Jay P. Das, Helena Chechik-Lankin and Ilan Marek*
Enantioselective Construction of all-Carbon Quaternary Stereogenic Carbons in Aldol Reactions
Nature Chemistry (2009), in press

131) Rozalia Unger, Fritz Weisser, Nicka Chinkov, Amnon Stanger, Theodore Cohen and Ilan Marek*
Diastereo- and Enantioselective Zinc ene-allene Carbocyclization
Org. Lett. (2009), in press

130) Samah Simaan and Ilan Marek*
Copper-Catalyzed Hydride Transfer from LiAlH4 for the Formation of Alkylidenecyclopropane Derivatives
Chem. Commun. (2009), 3, 292-294

129) Genia Sklute and Ilan Marek*
Carbozincation of Alkynes and Alkenes
Org. React. (2008) Submitted

128) Einav Tsoglin, Helena Chechik-Lankin, Guy Karzerboom, Nicka Chinkov, Amnon Stanger and Ilan Marek*
Stereoselective Synthesis of Metalated Cyclobutane Derivatives
Org. Lett. (2008) Submitted

127) Adi Abramovitch and Ilan Marek*
Zinc Homologation-Elimination reaction of α-Sulfinyl Carbanions as a New Route to Olefins
Eur. J. Org. Chem. (2008), 29, 4924-4931

126) Adi Abramovitch, Louis Fensterbank, Max Malacria and Ilan Marek*
Convergent Preparation of Enantiomerically Pure Polyalkylated Cyclopropane Derivatives
Angew. Chem. Int. Ed. (2008), 47, 6865-6868

125) Ilan Marek
A Shift in Retrosynthetic Paradigm (Concept Article)
Chem. Eur. J. (2008), 14, 7460-7468

124) Anat Levin and Ilan Marek*
Cyclopropenyllithiums as a New Source of 1,1-Bismetalated Cyclopropyl Derivatives
Chem. Commun. (2008), 36, 4300-4302

123) Bernhard Fuger, Genia Sklute, Ilan Marek, Gae Young Bolm, Carsten Bolm*
Synthesis of Sulfoximidoyl-Substituted Triazoles by Huisgen 1,3-Dipolar Cycloaddition
Synlett 2008, 1, 116-118

122) Theodore Cohen*, Heather Gibney, Roman Ivanov, Edmund A.-H. Yeh, Ilan Marek and Dennis P. Curran
Intramolecular Carbozincation of Unactivated Alkenes Occurs Through a Zinc Radical Transfer Mechanism
J. Am. Chem. Soc. (2007), 129, 15405-15409

121) Goren Kolodney, Genia Sklute, Sylvie Perrone, Paul Knochel and Ilan Marek*
Creation of Quaternary Stereogenic Centers in the Allylation Reaction of Sulfinilimines
Angew. Chem. Int. Ed. (2007), 46, 9291-9294

120) Ahmad Masarwa, Amnon Stanger and Ilan Marek*
An Efficient, Facile and General Stereoselective Preparation of Heterosubstituted Alkylidenecyclopropanes
Angew. Chem. Int. Ed. (2007), 46, 8039-8042

119) Ilan Marek*, Samah Simmaan, Ahmad Masarwa
Enantiomerically Enriched Cyclopropene Derivatives: Versatile Building Blocks in Asymmetric Synthesis
Angew. Chem. Int. Ed. (2007), 43, 7364-7376.

118) Ilan Marek* and Genia Sklute
Creation of Chiral Quaternary Stereocenters in the Carbonyl Allylation Reactions
Chem. Commun. (Feature article), (2007) 1683-1691

117) Samah Simaan and Ilan Marek*
Stereodivergent Carbometalation Reactions of Cyclopropenylcarbinols Derivatives
Org. Lett. (2007), 9, 2569-2571

116) Genia Sklute, Carsten Bolm and Ilan Marek*
Regio- and Stereoselective Copper-Catalyzed Carbozincation of Alkynylsulfoximines
Org. Lett. (2007), 9, 1259-1261.

115) Ilan Marek*, Nicka Chinkov and Anat Levin
A Zirconium Promenade; An Efficient Tool in Organic Synthesis
Synlett (account), 501-514 (2006)

114) Genia Sklute and Ilan Marek*
Multicomponent Approach for the Creation of Chiral Quaternary Centers in the Carbonyl Allylation Reactions
J. Am. Chem. Soc. (2006), 128, 4642-4649

113) Samah Simaan, Ahmad Masarwa, Philippe Bertus and Ilan Marek*
Chiral Cyclopropenylcarbinols as a New Source of Chiral Alkylidenecyclopropane Derivatives
Angew. Chem., Int. Ed., (2006), 45, 3963-3965

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112) Nicka Chinkov, Anat Levin and Ilan Marek*
Unsaturated Fatty Alcohol Derivatives as a New Source of Substituted Allylzirconocenes
Angew. Chem., Int. Ed., (2006), 45, 465-468

111) Rozalia Unger, Theodore Cohen and Ilan Marek*
New Tandem Zn-Promoted Brook Rearrangement/Ene-Allene carbocyclization Reactions
Org. Lett. (2005), 7, 5313-5316

110) Felix Kopp, Genia Sklute, Kurt Polborn, Ilan Marek and Paul Knochel*
Stereoselective Functionalization of Cyclopropane Derivatives Using Bromine/Magnesium and Sulfoxide/Magnesium Exchange Reactions
Org. Lett. (2005), 7, 3789-3791

109) Helena Chechik-Lankin and Ilan Marek*
Preparation and Synthetic Transformation of Alkenyl Carbamate into Vinyl Zirconocene Derivatives
Synthesis (2005), 3311-3318

108) Ilan Marek* and Helena Chechik-Lankin
Functionalized Organozirconium and Titanium in Organic Synthesis
In Functionalized Organometallic Derivatives
Ed. P. Knochel, Wiley-VCH, Weinheim, 2005, 503-540

107) Helena Chechik-Lankin, Shulamit Livshin and Ilan Marek*
Regiocontrolled Carbometallation Reactions of Ynamides
Synlett (2005), 2098-2100

106) Elinor Zohar, Amnon Stanger and Ilan Marek*
Synthesis of Chiral Methylenecyclopropanes Derivatives
Synlett (2005), 2239-2241

105) Ilan Marek
Ambiphilic Zinc Carbenoid as a New Tool for Multicomponent Condensation Reactions
Isr. J. Chem. (2004), 16, 22-32

104) Nicka Chinkov, Swapan Majumbar and Ilan Marek*
Stereoselective Synthesis and Reactivity of Dienyl Zirconocene
Practical Synthetic Procedures Synthesis, (2004), 2411-2417

103) Nicka Chinkov, Genia Sklute, Helena Chechik, Adi Abramovitch, Deborah Amsallem, Jos P. Varghese, Swapan Majumbar and Ilan Marek*
New Regio-, Stereo-, Diastereo-, and Enantioselective One-Pot Reactions Mediated by Organometallic Derivatives
Pure and Applied Chem. (2004) 76, 517-535

102) Nicka Chinkov and Ilan Marek*
Stereoselective Synthesis of Dienyl Zirconocenes Complexes
Topic in Organometallic Chemistry
Volume: New Aspects of Zirconium Containing Organic Compounds
Springer Verlag, (2004), 133-166

101) Frederic Leroux, Manfred Schlosser, Elinor Zohar and Ilan Marek
The Preparation of Organolithium Compounds and Derivatives
in The Chemistry of Organolithium Compounds
Eds Rappoport, Z.; Marek, I., John Wiley & Sons, Chichester, (2004), 435-493

100) Daniella Tene and Ilan Marek*
Carbometallation Reactions
in Transition Metals for Fine Chemicals and Organic Synthesis - 2nd Edition
Eds C. Bolm , M. Beller, Wiley-VCH, (2004), 563-573

99) Nicka Chinkov, Daniella Tene and Ilan Marek*
Carbometalation Reactions
in Metal-Catalyzed Cross-Coupling Reactions - 2nd Edition
Eds Diederich, F.; de Meijere, A. Wiley-VCH, (2004), 395-478

98) Elinor Zohar, Mirit Ram and Ilan Marek*
Stereoselective Preparation of Deuteriated Dienes by Ring Fragmentation of Metallated Cyclopropylcarbinols
Synlett (2004) 1288-1290

97) Stefan Wiedemann, Karsten Rauch, Andrei Savchenko, Ilan Marek, Armin de Meijere*
Convenient Access to 2-(Trialkylstannyl)cyclopropylamines and Their Application in Palladium-Catalyzed cross-Coupling Reactions
Eur. J. Org. Chem. (2004) 631-635

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96) Elinor Zohar and Ilan Marek*
Diastereoselective Reduction of Cyclopropenylcarbinol: new Access to Anti-Cyclopropylcarbinol Derivatives
Org. Lett. (2004), 6, 341-343

95) Adi Abramovitch, Jos P. Varghese, Ilan Marek*
α-Sulfinyl Carbanions as A New Source of Olefins
Org. Lett. (2004), 6, 621-623

94) Shahera Farhat, Irena Zouev and Ilan Marek*
From Vinyl Sulfides, Sulfoxides and Sulfones to Vinyl Zirconocene Derivatives
Tetrahedron (Special issue on Zirconium Chemistry by invitation only), (2004), 60, 1329-1337

93) Helena Chechik and Ilan Marek*
Regio- and Stereoselective Synthesis of Novel E-Alkenyl Carbamate via Carbocupration Reaction
Org. Lett. (2003) 5, 5087-5089

92) Nicka Chinkov, Swapan Majumbar and Ilan Marek*
Stereoselective Preparation of Dienyl Zirconocene Complexes via a Tandem Allylic C-H bond Activation-Elimination Sequence
J. Am. Chem. Soc. 125, 13258-13264, (2003)

91) Genia Sklute, Deborah Amsallem, Amal Shibli, Jos P. Varghese and Ilan Marek*
Four-Component Reactions for a New Diastereo- and Enantioselective Synthesis of Chiral Quaternary Centers
J. Am. Chem. Soc. 125, 11776-11777, (2003)

90) Ilan Marek*
Synthesis and Reactivity of Geminated Organobismetallic Derivatives
Actualite Chimique, special issue on the Present and future in Chemistry, 17-24, (2003) (Invited contribution)

89) Viet Anh Vu, Ilan Marek, Paul Knochel*
Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Compounds
Synthesis, 1797-1802, (2003)

88) Leila Motiei, Ilan Marek, Hugo Gottlieb, Vered Marks and Jean-Paul (Moshe) Lellouche*
Reaction of Allylzirconocene Compounds with Isolated or In Situ Generated η5 Pentadienyl Fe(CO)3/Fe(CO)2 PPh3(+1) Cations
Tetrahedron Lett. 44, 5909-5912, (2003)

87) Ilan Marek
Sp3 Organozinc Carbenoid Homologation in Organic Synthesis
Tetrahedron Report, 58, 9463-9475, (2002)

86) Nicka Chinkov, Swapan Majumdar, Ilan Marek*
New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence
J. Am. Chem. Soc. 124, 10282-10283, (2002)

85) Nicka Chinkov, Natalia Morlender-Vais, Ilan Marek*
New Preparation of Stereodefined α,β-Unsaturated Ketones by Carbomagnesiation of α-Allenyl Ketone
Tetrahedron lett. 43, 6009-6010, (2002)

84) Nicka Chinkov, Helena Chechik, Swapan Majumbar, Annie Liard and Ilan Marek*
New Methods for the Preparation of sp2 Organometallic Derivatives
Synthesis, Invited review, 2473-2483, (2002)

83) Jos P. Varghese, Irena Zouev, Lionel Aufauvre, Paul Knochel and Ilan Marek*
Carbocupration-Zinc Carbenoids Homologation and βElimination Reactions for a New Synthesis of Allenes. Applications to a New Synthesis of Chiral Allenes via Deracemization of sp3 Organometallic Derivatives
Eur. J. Org. Chem. 4151-4158, (2002)

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82) Eike Hupe, Ilan Marek and Paul Knochel*
Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers and Acyclic Molecules
Org. Lett. 4, 2861-2863, (2002)

81) Stefan Wiedemann, Ilan Marek, Armin de Meijere*
Functionalized Aminocyclopropanes from Functionalized Organozinc Compounds and N,N Dialkylcarboxamides.
Synlett 879-882, (2002)

80) Swapan Majumdar, Armin de Meijere and Ilan Marek*
Catalytic Asymmetric and Stereoselective Synthesis of Vinyl Cyclopropanes
Synlett 423-426, (2002)

79) Shahera Farhat and Ilan Marek*
From Vinyl Sulfides, Sulfoxides and Sulfones to Transition Metal Complexes
Angew. Chem. Int. Ed. 41, 1410-1413, (2002)

78) Viet Anh Vu, Ilan Marek, Kurt Polborn, Paul Knochel*
Preparation of New Functionalized Cyclopropylmagnesium Reagents
Angew. Chem. Int. Ed. 41, 351-352, (2002)

77) Annie Liard, Helena Chechik, Shahera Farhat, Natalia Morlender-Vais, Claudia Averbuj, Ilan Marek*
Oxidative Addition-β-elimination: A New Method for the Preparation of Organometallic Compounds
J. Organomet. Chem. 624, 26-33, (2001)

76) Hadi Rezaei, Ilan Marek, Jean F. Normant*
Diastereoselective Carbozincation of Propargylic Amines
Tetrahedron 57, 2477-2483 (2001)

75) Amal Shibli, Jos P. Varghese, Paul Knochel, Ilan Marek*
Improved Preparation of Secondary Zinc Iodides by 1,2-Migration of sp3 Carbenoids
Synlett 818-820 (2001)

74) Ilan Marek
Synthesis and Reactivity of sp2 Geminated Organobismetallics
Chem. Rev. 100, 2887-2900 (2000)

73) Natalia Vais-Morlender, Nicka Solodovnikova, Ilan Marek*
Carbometalation of Unactivated Alkynes via Low Valent Titanium Derivatives
Chem. Commun. 1849-1850 (2000)

72) Jos Varghese, Paul Knochel, Ilan Marek*
New Allene Synthesis via Carbocupration-Zinc Carbenoid Homologation and β-elimination
Org. Lett. 2, 2849-2852 (2000)

71) Annie Liard, Ilan Marek*
Stereoselective Preparation of E Vinyl Zirconium Derivatives from E or Z Enol Ether
J. Org. Chem. 7518-7220, 65, (2000)

70) Natalia Vais-Morlender, Julia Kaftanov and Ilan Marek*
First Synthesis and Reactivity of Functionalized Alkynyl Titanium Derivatives.
Synthesis, 917-920 (2000) Invited paper

69) Edwige Lorthiois*, Jean Normant, Ilan Marek
Novel Stereoselective and Enantioselective Synthesis of Heterocyclic Compounds by Anionic Method
Actual. Chim.(3), 60-61 (2000) Invited paper

68) Julia Kaftanov, Natalia Vais-Morlender, Claudia Averbuj, Annie Liard, Ilan Marek*
Synthesis and Reactivity of Polymetallated Olefins and Functionalized Metallo-Alkynes
Polyhedron Vol19/5, 563-566 (2000) Invited paper

67) Arindam Chakraborty and Ilan Marek*
New one-pot Synthesis of ω-Iodoalkyne
Synthetic Comm. 30, 1895-1901 (2000)

66) Benoit Folleas, Ilan Marek, Jean F. Normant*
Fluoroform: An Efficient Precursor for the Trifluoromethylation of Aldehydes
Tetrahedron 56, 275-283 (2000)

65) Ilan Marek
Enantioselective Carbometalation of Unactivated Olefins
J. Chem. Soc. Perkin Trans. 1, 535-544 (1999)

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64) Arindam Chakraborty, Ilan Marek*
Iodine Transfer Cyclization Mediated by DIBAL-H/THF
Chem. Commun. 2375-2376 (1999)

63) Lionel Aufauvre, Paul Knochel, Ilan Marek*
A New Approach towards the Synthesis of sp3 1,1-diiodoalkanes
Chem. Commun, 2207-2208 (1999)

62) Claudia Averbuj, Julia Kaftanov, Ilan Marek*
First Synthesis of Metallated Titanacyclopropenes
Synlett 11, 1939-1941 (1999)

61) Salvatore Avolio, Christophe Malan, Ilan Marek, Paul Knochel*
Preparation and Reaction of Functionalized Magnesium Carbenoids
Synlett 11, 1820-1822 (1999)

60) Ilan Marek, Peter R. Schreiner*, Jean F. Normant
The Allyl Zincation of Vinyl Metals. A Computational Study
Org. Lett. 1, 929-931 (1999)

59) Stephanie Norsikian, Ilan Marek*, Sophie Klein, Jean-Francois Poisson, Jean F. Normant*
Enantioselective Carbometalation of Cinnamyl Derivatives: New Access to Chiral Disubstituted Cyclopropanes. Configurational Stability of Benzylic Organozinc Halides
Chem. Eur. J. 5, 2055 (1999)

58) Nathalie Bremand, Ilan Marek*, Jean F. Normant*
Diastereoselective "Contra-Michael" Addition of (-)-Sparteine/Organolithium Complexes to Secondary Chiral Cinnamyl AIlan Marek* and Jean-F. Normantmides
Tetrahedron Lett. 40, 3383-3386 (1999)

57) Nathalie Bremand, Ilan Marek*, Jean F. Normant*
Regioselective Addition of nbutyllithium on Secondary Cinnamyl Amides: "Michael" Versus "Contra-Michael" Process
Tetrahedron Lett. 40, 3379-3382 (1999)

56) Isabelle Creton, Hadi Rezaei, Ilan Marek*, Jean F Normant*.
First Transfer of Chirality in the Fritsch-Buttenberg-Wiechell Rearrangement, via Zinc Carbenoids : A Migration with Retention of Configuration
Tetrahedron Lett. 40, 1899-1902 (1999)

55) Ilan Marek, Jean-F Normant
Preparation and Reaction of 1,η-bimetallic Reagents in Practical Approach in Organozinc Chemistry
Ed . Knochel, P. Oxford University Press, 119-137 (1998)

54) Ilan Marek, Jean-F Normant
Carbometallation Reactions in Metal-Catalyzed Cross-Coupling Reactions
Eds Stang, P.J., Diederich, F. Wiley-VCH, 271-337 (1998)

53) Ilan Marek, Jean-F Normant
Carbometalation Reactions in Transition Metals for Fine Chemicals and Organic Synthesis
Eds. Bolm, C., Beller, C. Wiley-VCH, 514-522 (1998)

52) Denis Brasseur, Ilan Marek*, Jean F. Normant*
Diastereoselective Carbometalation of Chiral Vinyl Metals
C. R. Acad. Sci. Paris, t.1, Serie II c 621-625 (1998)

51) Denis Brasseur, Hadi Rezaei, Alain Fuxa, Alex Alexakis, Pierre Mangeney, Ilan Marek*, Jean F. Normant*
First Diastereoselective carbometalation of Chiral Vinyl Metals
Tetrahedron Lett. 39, 4821-4824 (1998)

50) Benoit Folleas, Ilan Marek*, Jean-F. Normant* and Laurent Saint Jalmes
Fluoroform: An Efficient Precursor for the Trifluoromethylation of Carbonyl Compounds
Tetrahedron Lett. 39, 2973-2976 (1998)

49) Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Diastereoselective and Enantioselective Intramolecular Amino-Zinc-Enolate Carbometalation Reactions. A New Polysubstituted Pyrrolidines Synthesis
J. Org. Chem. 63, 2442-2450 (1998)

48) Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Amino-Zinc-Enolate carbocyclization reactions. New Access to Polysubstituted Piperidines Derivatives
J. Org. Chem. 64, 566-574 (1998)

47) Stephanie Norsikian, Ilan Marek*, Jean-F. Normant*
Enantioselective Carbolithiation of β-alkylated Styrene
Tetrahedron Lett. 38, 7523-7526 (1997)

46) Stephanie Norsikian, Ilan Marek*, Jean-Francois Poisson, Jean-F. Normant*
Enantioselective Carbolithiation of Cinnamyl Acetals. New Access to Chiral Disubstituted Cyclopropanes
J. Org. Chem. 62, 4898-4899 (1997)

45) Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Zinca-ene-allene Cyclizations. A way to Substituted Tetrahydrofurans or Pyrrolidines
Bull. Soc. Chim. Fr. 134, 333-341 (1997)

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44) Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Zinca-en-allene and Zinc-enolate Cyclization. Towards the Synthesis of Polysubstituted Pyrrolidines
Tetrahedron Lett. 1997, 38, 89-92 (1997)

43) Ilan Marek, Christophe Meyer and Jean-F. Normant
A Simple and Convenient Method for the Preparation of (Z) or (E)-γ-Iodo Allylics Alcohols and (Z)-β-Iodo Acrolein
Org. Synth. 74, 194-204 (1997)

42) Ilan Marek* and Jean-F. Normant
Synthesis and Reactivity of sp3 Geminated Organobismetallics
Chem. Rev. 96, 3241-3267 (1996)

41) Isabelle Creton, Ilan Marek* and Jean-F. Normant*
Synthesis of Polysubstituted Stereodefined Olefins via the Reactivity of sp2 Organogembismetallics
Synthesis 1499-1508 (1996)

40) Edwige Lorthiois, Ilan Marek* and Jean-F. Normant*
Intramolecular Carbolithiation of Silylated Enynes
Tetrahedron Lett. 37, 6693-6694 (1996)

39) Edwige Lorthiois, Ilan Marek*, Christophe Meyer and Jean-F. Normant*
Intermolecular Carbolithiation of Silylated Enynes
Tetrahedron Lett. 37, 6689-6692 (1996)

38) Anja Bahr, Ilan Marek* and Jean-F. Normant*
Diastereoselective Carbometalation of δ-Mono and γ-λ-Disubstituted Z Vinyl Metals
Tetrahedron Lett. 37, 5873-5876 (1996)

37) Christophe Meyer, Ilan Marek* and Jean-F. Normant*
Stereoselective Synthesis of Linear and Angular Triquinanes Skeletons via the Zinca-Ene Allene Reactions
Tetrahedron Lett. 37, 857-860 (1996)

36) Denis Brasseur, Ilan Marek* and Jean-F. Normant*
Diastereoselective Synthesis of Heterosubstituted Organogembismetallic Reagents. Application to a New Propargylmetalation Reaction of Vinyl Metals
Tetrahedron 52, 7235-7250 (1996)

35) Isabelle Creton, Ilan Marek* and Jean-F. Normant*
Stereoselective Synthesis of Polysubstituted Olefins via the Formation of 1,1-Bimetalloalkenes
Tetrahedron Lett. 36, 7451-7454 (1995)

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34) Sophie Klein, Ilan Marek*, Jean Francois Poisson and Jean-F. Normant*
Asymmetric Carbolithiation of Cinnamyl Derivatives in the Presence of (-) Sparteine
J. Am. Chem. Soc. 117, 8853-8854 (1995)

33) Fan Wang, Jie Tang, Lydie Labaudiniere, Ilan Marek* and Jean-F. Normant*
Diastereoselective Reactions of Gembismetallic Derivatives
Synlett 723-7251 (1995)

32) Ilan Marek*, Dov Beruben and Jean-F. Normant*
Metal-Alkene π-Chelation: A Stereodirecting Effect in Allylzincation Reactions and in Zinc Mediated Cyclopropanations
Tetrahedron Lett. 36, 3695-3698 (1995)

31) Dov Beruben, Ilan Marek*, Jean-F. Normant and Nicole Platzer
Stereodefined Substituted Cyclopropyl Zinc Reagents from Gembismetallics
J. Org. Chem. 60, 2488-2501 (1995)

30) Edwige Lorthiois, Ilan Marek*, Christophe Meyer and Jean-F. Normant*
Zinca-En-Allene Cyclization. Synthesis of Substituted Tetrahydrofurans
Tetrahedron Lett. 36, 1263-1266 (1995)

29) Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
Intramolecular Metallo-Ene-Allene Reactions. A New Carbocycles Synthesis
J. Org. Chem. 60, 863-871 (1995)

28) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Diastereoselective Carbometalation of γ-Heterosubstituted Vinylmetals
Bull. Soc. Chim. Fr. 131, 910-918 (1994)

27) Isabelle Creton, Ilan Marek*, Denis Brasseur, Jean-Luc Jestin and Jean-F. Normant*
Phenylthioacetylene as a Source of Stereodefined Trisubstituted Alkenes
Tetrahedron Lett. 35, 6873-6876 (1994)

26) Christophe Meyer, Ilan Marek*, Jean-F. Normant and Nicole Platzer*
Carbocyclization of δ-acetylenic Propargylic Zinc Reagents
Tetrahedron Lett. 35, 5645-5648 (1994)

25) Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
Intramolecular Carbometallation of Organozinc Reagents
Tetrahedron 50, 11665-11692 (1994)

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24) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Diastereoselective Carbometalation of Vinyl Metals
J. Org. Chem. 59, 4154-6166 (1994)

23) Sophie Klein, Ilan Marek* and Jean-F. Normant*
Carbolithiation of Cinnamyldialkylamines. Stereochemistry of the Li to Zn Transmetalation and Configurational Stability of Benzylic Organozinc Halides
J. Org. Chem. 59, 2925-2926 (1994)

22) Dov Beruben, Ilan Marek*, Jean-F. Normant* and Nicole Platzer
Cyclic Steocontrol Via Organobismetallic Reagents. Part VI. Stereodefined Substituted Cyclopropyl Zinc Reagents
Tetrahedron Lett. 34, 7575-7578 (1993)

21) Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
Intramolecular Carbometallation of Secondary Organozinc Reagents
Tetrahedron Lett.34, 6053-6056 (1993)

20) Fabrice Chemla*, Ilan Marek and Jean-F. Normant*
Selective Monoalkylation of Organogembismetallics via an Intramolecular Nucleophilic Substitution
Synlett 665-666 (1993)

19) Christophe Meyer, Ilan Marek* and Jean-F. Normant*
(E)-or (Z)-β-iodoacrolein: A Novel Versatile Synthon
Synlett 386-388 (1993)

18) Christophe Meyer, Ilan Marek* and Jean-F. Normant*
Carbocyclisation of Functionnalized Zinc Organometallics
Synlett 266-268 (1993)

17) Dov Beruben, Ilan Marek*, Lydie Labaudiniere and Jean-F. Normant*
Cyclic Stereocontrol Via Organobismetallic Reagents. Part V. Diastereoselective Synthesis of Substituted Cyclopropyl Zinc Reagents by the Metalla-Claisen Reaction
Tetrahedron Lett. 34, 2303-2306 (1993)

16) Alex Alexakis*, Pierre Mangeney, Ilan Marek, Francoise Rose-Munch, Eric Rose, Assia Semra and Francis Robert
Resolution and Asymmetric Synthesis of Ortho-Substituted (Benzaldehyde) Tricarbonylchromium Complexes
J. Am. Chem. Soc. 114, 8288-8290 (1992)

15) Jean-F. Normant, Ilan Marek and Jean-Michel Lefrancois
Organobismetallic Zinc Reagents: Their Preparation and Use in Diastereoselective Reactions
Pure and Appl. Chem. 64, 1857-1864 (1992)

14) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Acyclic Stereocontrol Via Organogembismetallic Reagents. Part III
Synlett 633-634 (1992)

13) Ilan Marek, Alex Alexakis*, Pierre Mangeney and Jean-F. Normant
Synthese d'Alcoxyallenes Chiraux par Carbocupration d'Acetals Propargyliques. Etude de Leur Reactivite à l'egard d'Organocuprates
Bull. Soc. Chem. Fr. 129, 171-190 (1992)

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12) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Iodocyclisation of Olefinic t-butyl Ethers: An Easy Stereocontrolled Synthesis of Cis-Substituted Tetrahydrofurans
Tetrahedron Lett. 33, 1747-1748 (1992)

11) Ilan Marek*, Alex Alexakis and Jean-F. Normant*
γ-tributylstannyl-b-metallated Acrolein: A Versatile Synthon
Tetrahedron Lett. 32, 6337-6340 (1991)

10) Ilan Marek* and Jean-F. Normant,
Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part II
Tetrahedron Lett. 32, 5973-5976 (1991)

9) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Acyclic Stereocontrol Through the Metalla-Claisen Rearrangement. Part I
Tetrahedron Lett. 32, 5969-5972 (1991)

8) Ilan Marek*, Alex Alexakis and Jean-F. Normant
A Highly Efficient Synthesis of (Z)-γ-iodo Allylic Alcohols
Tetrahedron Lett. 32, 5329-5332 (1991)

7) Alex Alexakis*, Ilan Marek, Pierre Mangeney and Jean-F. Normant
Diastereoselective Syn or Anti Opening of Propargylic Epoxides. Synthesis of α-allenic Alcohols
Tetrahedron 47, 1677-1696 (1991)

6) Alex Alexakis*, Ilan Marek, Pierre Mangeney, Jean-F. Normant
Mechanistic Aspects on the Formation of Chiral Allenes From Propargylic Ethers and Organocopper Reagents
J. Am. Chem. Soc. 112, 8042-8047 (1990)

5) Jean-P. Declercq* and Ilan Marek
Structure of 1,3,5-triallyl-4,6-diphenyl-1,3,5-triazacyclohexan-2- -one
Acta. Cryst., C46, 1168-1170 (1990)

4) Alex Alexakis*, Ilan Marek, Pierre Mangeney, Jean-F. Normant
Copper-Catalyzed Reductive Metallation of a Propargylic Epoxide to an Allenyl Lithium Reagent
Tetrahedron. Lett. 30, 2391-2392 (1989)

3) Alex Alexakis*, Ilan Marek, Pierre Mangeney, Jean-F. Normant
Diastereoselective Synthesis of α-Allenic Alcohols from Propargylic Epoxides
Tetrahedron. Lett. 30, 2387-2390 (1989)

2) Alex Alexakis*, Pierre Mangeney, Abdellaziz Ghribi, Ilan Marek, Richard Sedrani, Christophe Guir and Jean-F. Normant
Chiral Acetals in Enantio-and Diastereoselective Substitution or Elimination Reactions
Pure & Appl.Chem. 60, 49-56 (1988)

1) Ilan Marek, Pierre Mangeney, Alex Alexakis* and Jean-F. Normant
Are Allenes Formed from Propargylic Ethers Through a Syn or Anti-Displacement?
Tetrahedron Lett. 27, 5499-5502 (1986)

Books

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6) Zvi Rappoport and Ilan Marek (Editors)
The Chemistry of Organomagnesium Compounds
John Wiley & Sons, Chichester, England, 2008, 890 pages

5) Zvi Rappoport and Ilan Marek (Editors)
The Chemistry of Organozinc Compounds
John Wiley & Sons, Chichester, England, 2006, 1100 pages

4) Zvi Rappoport and Ilan Marek (Editors)
The Chemistry of Organolithium Compounds Part 2
Patai's series
John Wiley & Sons, Chichester, England, 2005, 740 pages

3) Ilan Marek (Editor)
Topic in Organometallic Chemistry
Volume: New Aspects of Zirconium Containing Organic Compounds
Springer Verlag, 2005, 170 pages

2) Zvi Rappoport and Ilan Marek (Editors)
The Chemistry of Organolithium Compounds. Part 1
Patai's series
John Wiley & Sons, Chichester, England, 2004, 1400 pages

1) Ilan Marek (Editor)
Titanium and Zirconium in Organic Synthesis
Wiley-VCH, May 2002, 500 pages

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Miscellaneous:

1) Ilan Marek
Preface for a special issue of the Journal of Organometallic Chemistry dedicated to Prof. Jean F. Normant
J. Organomet. Chem. 624, 1-3, (2001)

2) Ilan Marek
Guest Editor for a special issue of Tetrahedron Symposium-in-Print on Multicomponent Reactions
Tetrahedron, (2005), 61, 11309-11519

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David Eisenberg - Professite