Zeev GROSS: List of publications

 

1.        S. Hoz, Z. Gross and D. Cohen; "p Nucleophilicity:  The Effect of Charge Delocalization on the Efficiency of Internal Displacements in E1cB Reactions." J. Org. Chem. 1985, 50, 832 - 836.

2.        S. Hoz, Z. Gross and D. Speizman; "Nucleophilic Attacks on LL (Low LUMO) Substrates. Part  3.  Molecular Stacking of 9-methylenefluorene Derivatives as a Source of Zero-order Reactions." J. Chem. Soc., Perkin Trans. 2  1985, 1143 - 1146.

3.        Z. Gross and S. Hoz; "Radical-anionic Nature of the Transition State in the Michael Addition Reaction." J. Am. Chem. Soc. 1988, 110, 7489 - 7493.

4.        Z. Gross and S. Hoz; "Curve Crossing Analysis and Rate - ¹³C Chemical Shift Correlation in Michael Reaction." Tetrahedron Lett. 1991, 32, 5163 - 5166.

5.        Z. Gross and S. Hoz; "Curve Crossing Analysis of LFER Data in Michael Addition Reactions."  Can. J. Chem. 1992, 70, 1022 - 1027.

6.        Z. Gross and C. Barzilay; "Spectroscopic Characterization of Two Types of Tetraarylporphyrin Cation Radicals."  Angew. Chem. Int. Ed. Eng. 1992, 31, 1615 - 1617. Angew. Chem. 1992, 104, 1672 - 1674.

7.        Z. Gross and S. Nimri; "A Pronounced Axial Ligand Effect on the Reactivity of Oxoiron(IV) Porphyrin Cation Radicals." Inorg. Chem. 1994, 33, 1731-2.

8.        J. T. Groves, Z. Gross and M. K. Stern; "Preparation and Reactivity of Oxoiron(IV) Porphyrins." Inorg. Chem. 1994, 33, 5065 - 5072.

9.        Z. Gross and I. Toledano; "Preparation of Bis-Pocket Porphyrins with Carboxylic Acid Synthons." J. Org. Chem. 1994, 59, 8312-5.

10.    C. M. Barzilay, S. A. Sibilia, T. G. Spiro, and Z. Gross; "Elucidation of Factors Affecting the Electronic Structures of Magnesium(II) and Zinc(II) Tetraarylporphyrin Cation Radicals" Chem. Eur. J. 1995, 1, 312-321.

11.    J. T. Groves and Z. Gross; "On the Mechanism of Epoxidation and Hydroxylation Catalyzed by Iron Porphyrins. Evidence for Non-Intersecting Reaction Pathways", Bioinorganic Chemistry: An Inorganic Perspective of Life, D. P. Kessissoglou, Ed., Kluwer Academic Publishers, Dordtrecht, NATO ASI Series, Vol. 459, 1995, 39-47.

12.    Z. Gross and C. M. Barzilay; "A Novel Facile Synthesis of Dihalogenoruthenium(IV) Porphyrins" J. Chem. Soc., Chem. Commun. 1995, 1287-8.

13.    Z. Gross and L. Kaustov; "New Efficient Routes for the Preparation of Deuterated Tetraarylporphyrins" Tetrahedron Lett. 1995, 36, 3735-6.

14.    Z. Gross and S. Nimri; "Seeing the Long Sought Intermediate in the Reaction of Oxoiron(IV) Porphyrin Cation Radicals with Olefins" J. Am. Chem. Soc. 1995, 117, 8021-2.

15.    C. M. Barzilay, S. A. Sibilia, T. G. Spiro, and Z. Gross; "Tuning the Intramolecular Spin Coupling in Metalloporphyrin Cation Radicals" J. Inorg. Biochem. 1995, 59, 517.

16.    S. Ini, M. Kapon, S. Cohen, and Z. Gross; "Self Assembly Assisted Preparation of a Homochiral Porphyrin" Tetrahedron: Asymmetry  1996, 7, 659-62.

17.    K. Czarnecki, S. Nimri, Z. Gross, L. M. Proniewicz, and J. R. Kincaid; "Direct Resonance Raman Evidence for a Trans Influence on the Ferryl Fragment in Models of Compound I Intermediates of Heme Enzymes" J. Am. Chem. Soc. 1996, 118, 2929-35.

18.    Z. Gross, S. Ini, M. Kapon, and S. Cohen; "First Utilization of a Homochiral Ruthenium Porphyrin as Enantioselective Epoxidation Catalyst" Tetrahedron Lett. 1996, 37, 7325-8.

19.    Z. Gross; "The Effect of Axial Ligands on the Reactivity and Stability of the Oxoferryl Moiety in Model Complexes of Compound I of Heme-dependant Enzymes" J. Biol. Inorg. Chem. 1996, 1, 368-71.

20.    Z. Gross, S. Nimri, and L. Simkhovich; "Iron Porphyrin Catalyzed Hydroxylation of Ethylbenzene by Ozone" J. Mol. Cat. 1996, 113, 231-8.

21.    Z. Gross and A. Mahammed; "One-pot Synthesis of Dihalo(porphyrinato)­osmium(IV) Complexes. Evidence for Monohalo(carbonyl)osmium(III) Intermediates" Inorg. Chem. 1996, 35, 7260-3.

22.    Z. Gross and L. Simkhovich; "Ozone as Primary Oxidant in Iron(III) Porphyrin Catalyzed Hydroxylation of Hydrocarbons" J. Mol. Cat. 1997, 117, 243-8.

23.    Z. Gross, I. Saltsman, R. P. Pandian, and C. M. Barzilay; "The First Metal Chelation by a Neutral Porphyrin Analogue" Tetrahedron Lett. 1997, 38, 2383-6.

24.    L. Kaustov, M. E. Tal, A. I. Shames, and Z. Gross; "Spin Transition in a Manganese(III) Porphyrin Cation Radical, Its Transformation to a Dichloromanganese(IV) Porphyrin, and Chlorination of Hydrocarbons by the Latter" Inorg. Chem. 1997, 36, 3503-3511

25.    Z. Gross and S. Ini; "Remarkable Effects of Metal, Solvent, and Oxidant on Metalloporphyrin Catalyzed Enantioselective Epoxidation of Olefins" J. Org. Chem. 1997, 62, 5514-5521.

26.    Z. Gross, S. Nimri, C. M. Barzilay, and L. Simkhovich; "Reaction Profile of the Epoxidation of Olefins by Oxoiron(IV) Porphyrin Cation Radical Complexes, Models of the Last Step in Cytochrome P-450 Catalysis", J. Biol. Inorg. Chem. 1997, 2, 492-505.

27.    Z. Gross; "Thermodynamic and Kinetic Effects of Axial Ligands in Compound I Analogues of Cytochrome P-450." FASEB J. 1997, 11, A780.

28.    Z. Gross, A. Mahammed, and C. M. Barzilay; "Halogen to Metal p-Bonding in Metalloporphyrins", J. Chem. Soc., Chem. Commun. 1998, 1505-6.

29.    Z. Gross and L. Simkhovich; "Hydroxylation of Simple Alkanes by Iodosylbenzene is Catalyzed more Efficiently by Second than by Third Generation Iron(III) Porphyrins", Tetrahedron Lett. 1998, 39, 8171-4.

30.    A. Segev, D. Aviezer, Z. Gross, and A. Yayon; "Inhibition of Vascular Smooth Cell Proliferation by a Novel Fibroblast Growth Factor Receptor Antagonists." 70th Am. Heart Assoc. 1998, A104549.

31.    Z. Gross, N. Galili, and L. Simkhovich; "Metalloporphyrin Catalyzed Asymmetric Cyclopropanation of Olefins", Tetrahedron Lett. 1999, 40, 1571-4.

32.    Z. Gross and S. Ini; "Dual Role of  Pyridine N-oxides in Ruthenium Porphyrin Catalyzed Asymmetric Epoxidation of Olefins.", Inorg. Chem. 1999, 38, 1446-9.

33.    Z. Gross, N. Galili, and L. Simkhovich; "Corroles, Ligands of the Future", J. Inorg. Biochem. 1999, 74, 27.

34.    Z. Gross, N. Galili, and I. Saltsman; "The First Direct Synthesis of Corroles from Pyrrole", Angew. Chem. Int. Ed. Eng. 1999, 38, 1427-9.

35.    Z. Gross, L. Simkhovich, and N. Galili; "First Catalysis by Corrole Metal Complexes: Epoxidation, Hydroxylation, and Cyclopropanation", J. Chem. Soc., Chem. Commun. 1999, 599-600.

36.    Z. Gross and A. Mahammed; "Novel Reactivities of Iodosylbenzene in the Catalytic Oxygenation of Olefins", J. Mol. Cat. 1999, 142, 367-372.

37.    Z. Gross and N. Galili; "N-Substituted Corroles, a Novel Class of Chiral Ligands", Angew. Chem. Int. Ed. Eng. 1999, 38, 2366-2369.

38.    Z. Gross, N. Galili, L. Simkhovich, I. Saltsman, M. Botoshansky, D. Bläser, R. Boese, and I. Goldberg; "Solvent-Free Condensation of Pyrrole and Pentafluorobenzaldehyde: A Novel Synthetic Pathway to Corrole and Oligopyrromethenes", Org. Lett. 1999, 1, 599-602.

39.    Z. Gross and S. Ini; "Asymmetric Catalysis by a Chiral Ruthenium Porphyrin: Epoxidation, Hydroxylation and Partial Kinetic Resolution of Hydrocarbons", Org. Lett. 1999, 1, 2077-2080.

40.    D. Aviezer, S. Cotton, M. David, A. Segev, N. Khaselev, N.Galili, Z. Gross, and A. Yayon; "Porphyrin Analogues as Novel Antagonists of Fibroblast Growth Factor and Vascular Endotherial Growth Factor Receptor Binding that Inhibit Endothelial Cell Proliferation, Tumor Progression, and Metastasis", Cancer Research 2000, 60,  2973-2980.

41.    L. Simkhovich, N. Galili, I. Saltsman, I. Goldberg, and Z. Gross; "Coordination Chemistry of the Novel 5,10,15-tris(pentafluorophenyl)corrole: Synthesis, Spectroscopy, and Structural Characterization of its Cobalt(III), Rhodium(III), and Iron(IV) Complexes", Inorg. Chem. 2000, 39, 2704-5.

42.    L. Simkhovich, I. Goldberg, and Z. Gross; "First Syntheses and X-ray Structures of a Meso-alkyl Substituted Corrole and its Ga(III) Complex", J. Inorg. Biochem. 2000, 80, 235-238.

43.    A. E. Meier-Callahan, H. B. Gray, and Z. Gross; "Stabilization of High-Valent Metals by Corroles: Oxo[Tris(pentafluorophenyl)corrolato]chromium(V)", Inorg. Chem., 2000, 39, 3605-3607.

44.    Z. Gross, G. Golubkov, and L. Simkhovich; "Epoxidation Catalysis by a Manganese(III) Corrole and Isolation of an Oxomanganese(V) Corrole", Angew. Chem. Int. Ed. Eng. 2000, 39, 4045-4047.

45.    J. Bendix, G. Golubkov, H. B. Gray, and Z. Gross; "High Field (High Frequency) EPR Spectroscopy and Structural Characterization of a Novel Manganese(III) corrole", J. Chem. Soc., Chem. Commun. 2000, 1957-1958.

46.    J. Bendix, I. J. Dmochowski, H. B. Gray, A. Mahammed, L. Simkhovich, and Z. Gross; "Structural, Electrochemical, and Photophysical Properties of Gallium(III) 5,10,15-tris(pentafluorophenyl)corrole", Angew. Chem. Int. Ed. Eng. 2000, 39, 4048-4051.

47.    L. Simkhovich, A. Mahammed, I. Goldberg, and Z. Gross; " Synthesis and Characterization of Germanium, Tin, Phosphorous, Iron, and Rhodium Complexes of Tris(pentafluorophenyl)corrole, and the Utilization of the Iron and Rhodium Corroles as Cyclopropanation Catalysts", Chem. Eur. J. 2001, 7, 1041-1055.

48.    G. Golubkov, J. Bendix, H. B. Gray, A. Mahammed,  I. Goldberg, A. J. DiBilio, and Z. Gross; "High Valent Manganese Corroles and the First Perhalogenated Corrole-Based Catalyst", Angew. Chem. Int. Ed. Eng. 2001, 40, 2132-2134.

49.    L. Simkhovich,  S. Rosenberg, and Z. Gross; "Facile Synthesis of a Novel Sapphyrin and its Rhodium(I) Complex", Tetrahedron Lett. 2001, 42, 4929-4931.

50.    Z. Gross; "High Valent Corrole Metal Complexes", J. Biol. Inorg. Chem. 2001, 6, 733-738.

51.    A. Mahammed,  I. Giladi, I. Goldberg, and Z. Gross; "Synthesis and Structural Characterization of a Novel Covalently-Bound Corrole Dimer ", Chem. Eur. J. 2001, 7, 4259-4265.

52.    L. Simkhovich and Z. Gross; "Iron(IV) Corroles are Potent Catalysts for Aziridination of Olefins by Chloramine-T”, Tetrahedron Lett. 2001, 42, 8089-8092.

53.    A. Mahammed,  I. Goldberg, and Z. Gross; "Highly Selective Chlorosulfonation of Tris(pentafluorophenyl)corrole as a Synthetic Tool for the Preparation of Amphiphilic Corroles and Metal Complexes of Chiral Planarity”, Org. Lett. 2001, 3, 3443-3446.

54.    S.P. de Visser, F. Ogliaro, Z. Gross and S. Shaik; “What is the Difference Between the Manganese Porphyrin and Corrole Analogs of Cytochrome P450’s Compound I", Chem. Eur. J. 2001, 7, 4954-4960.

55.    A. E. Meier-Callahan, A. J. Di Bilio, L. Simkhovich, A. Mahammed, I. Goldberg, H. B. Gray, and Z. Gross; "Chromium Corroles in Four Different Oxidation States”, Inorg. Chem. 2001, 40, 6788-6793.

56.    A. Mahammed and Z. Gross; "Aluminum Corrolin, a Novel Chlorophyll Analogue”, J. Inorg. Biochem. 2002, 88, 305-309.

57.    A. Segev, D. Aviezer, M. Safran, Z. Gross, and A. Yayon; "Inhibition of Vascular Smooth Muscle Cell Proliferation by a Novel Fibroblast Growth Factor Receptor Antagonist", Cardiovasc. Res. 2002, 53, 232-241.

58.    J. Grodkowski, P. Neta, E. Fujita, A. Mahammed, L. Simkhovich, and Z. Gross; "Reduction of Cobalt and Iron Corroles and Catalyzed Photoreduction of CO₂”, J. Phys. Chem. A 2002, 106, 4772-4778.

59.    L. Simkhovich, P. Iyer, I. Goldberg, and Z. Gross; “Structure and Chemistry of N-substituted Corroles and their Rhodium(I) and Zinc(II) Metal-Ion Complexes”, Chem. Eur. J. 2002, 8, 2595-2601.

60.    I. Saltsman, A. Mahammed, I. Goldberg, E. Tkachenko, M. Botoshansky, and Z. Gross; “Selective Substitution of Corroles: Nitration, Hydroformylation, and Chlorosulfonation”, J. Am. Chem. Soc. 2002, 124, 7411-7420.

61.    L. Simkhovich,  I. Goldberg, and Z. Gross; “Iron(III) and Iron(IV) Corroles: Synthesis, Spectroscopy, Structures, and no Indications for Corrole Radicals”, Inorg. Chem. 2002, 41, 5433-5439.

62.    L. Simkhovich, I. Goldberg, and Z. Gross; “The Effects of Bulky ortho-Aryl Substituents in Corroles, Tested by X-ray Crystallography of the Rhodium Complexes and Catalysis thereby”, J. Porphyrins Phthalocyanines 2002, 6, 439-444.

63.    Z. Gross and A. Mahammed; “Selective Sulfonation and Deuteration of Free-base Corroles”, J. Porphyrin Phthalocyanines 2002, 6, 553-555.

64.    L. Simkhovich, I. Luobeznova, I. Goldberg, and Z. Gross; “Mono- and Binuclear Ruthenium Corroles: Synthesis, Spectroscopy, Electrochemistry, and Structural Characterization”, Chem. Eur. J.  2003, 9, 201-208.

65.    A. Mahammed, H. B. Gray, A. E. Meier-Callahan, and Z. Gross; “Aerobic Oxidations Catalyzed by Chromium Corroles”, J. Am. Chem. Soc. 2003, 125,  1162-1163.

66.    A. Mahammed, H. B. Gray, J. Weaver, and Z. Gross; “How Acidic are Corroles and Why?”, Tetrahedron Lett. 2003, 44, 2077-2079.

67.    L. Simkhovich, I. Goldberg, and Z. Gross; ”Easy Preparation of Cobalt Corrole and Hexaphyrin and Isolation of New Oligopyrroles in the Solvent-Free Condensation of Pyrrole with Pentafluorobenzaldehyde”, Org. Lett. 2003, 5, 1241-1244.

68.    I. Saltsman, I. Goldberg, and Z. Gross; “One-step Conversions of a Simple Corrole into Chiral and Amphiphilic Derivatives”, Tetrahedron Lett. 2003, 44, 5669-5673.

69.    G. Golubkov and Z. Gross; “Chromium(V) and Chromium(VI) Nitrido Complexes of Tris(pentafluorophenyl)corrole”, Angew. Chem. Int. Ed. 2003, 42, 4507-4510.

70.    I. Luobeznova, L. Simkhovich, I. Goldberg, and Z. Gross; “Electronic structures and Reactivities of Copper-Corrole Complexess” Eur. J. Inorg. Chem.2004, 1724-1732.

71.    Y. S. Balazs, I. Saltsman, A. Mahammed, E. Tkachenko, G. Golubkov, J. Levine, and Z. Gross; “High Resolution NMR Spectroscopic Trends of Corrole Complexes: Assignment Rules of Metal-free, Metallated, and Substituted Corroles”, Magn. Reson. Chem. 2004, 42, 624-635.

72.    E. Stavitski, A. Berg, T. Ganguly, A. Mahammed, Z. Gross, and H. Levanon ; “Electron Spin Dynamics in Photoexcited Diamagnetic and Paramagnetic Corroles”  J. Am. Chem. Soc 2004, 126, 6886-6890.

73.    I. Saltsman, L. Simkhovich, Y. S. Balazs, I. Goldberg, and Z. Gross; “Synthesis, Spectroscopy, and Structures of New Rhodium(I) and Rhodium(III) Corroles and Catalysis Thereby”, Inorg. Chim. Acta 2004, 357, 3038-3046.

74.    A. Mahammed,  H. B. Gray, J. J. Weaver, K. Sorasaenee, and Z. Gross; “Amphiphilic Corroles Bind Tightly to Human Serum Albumin”, Bioconj. Chem. 2004, 15, 738-746.

75.    Z. Gross and Harry B. Gray; “Oxidations Catalyzed by Metallocorroles” Adv. Syn. Cat. 2004, 346, 165-170.

76.    L. Simkhovich and Z. Gross; “Halogeno-Coordinated Iron Corroles”, Inorg. Chem. 2004, 43, 6136-6138.

77.    J. J. Weaver, K. Sorasaenee, M. Sheikh, R. Goldschmidt, E. Tkachenko, Z. Gross, and H. B. Gray; “Gallium(III) Corroles”, J. Porphyrins Phthalocyanines 2004, 8, 76-81.

78.    A. Mahammed and Z. Gross; “Albumin-Conjugated Corrole Metal Complexes: Extremely Simple, Yet very Efficient Biomimetic Oxidation Systems” , J. Am. Chem. Soc. 2005, 127, 2883-2887.

79.    G. Golubkov and Z. Gross; “Nitrogen Atom Transfer between Manganese Complexes of Salen, Porphyrin, and Corrole and Characterization of a (Nitrido)manganese(VI) Corrole”, J. Am. Chem. Soc. 2005, 127, 3258-3259.

80.    I. Luobeznova,^. M. Raizman,^. I. Goldberg. and Z. Gross; “Synthesis and Full Characterization of Molybdenum and Antimony Corroles and Utilization of the Latter Complexes as Very Efficient Catalysts for Highly Selective Aerobic Oxygenation Reactions” Inorg. Chem. 2006, 45, 386-394.

81.    H. Agadjanian, J. J. Weaver, A. Mahammed, A. Rentsendorj, S. Bass, J. Kim, I. J. Dmochowski, R. Margalit, H B. Gray, Z. Gross, and L. K. Medina-Kauwe; “Specific Delivery of Corroles to Cells via Noncovalent Conjugates with Viral  Proteins”, Pharmaceutical Res. 2006, 23, 367-377.

82.    I. Aviv and Z. Gross; “Iron Corroles and Porphyrins as Very Efficient and Highly Selective Catalysts for the Reactions  of a-Diazo Esters with Amines”, Synlett 2006, 951-953.

83.    I. Saltsman, Y. Balazs, I. Goldberg, and Z. Gross; “Synthesis, Spectroscopy, and Structures of Chiral Rhodium(I) Corrole Complexes” , J. Mol. Cat. A: Chemical 2006, in press.

84.    Z. Gross and H. B. Gray; “How do corroles stabilize high valent metals?”, Comm. Inorg. Chem 2006, 27, accepted for publication.

85.    R. Goldschmidt, I. Goldberg, Y. Balazs, and Z. Gross; “Synthesis of Corroles with Small and Stabilizing Substitutents”, J. Porphyrins Phthalocyanines 2006, 10, accepted for publication.

 

PATENTS

1.    N. Galili-Nachshon, L. Simkhovich, Z. Gross, I. Saltsman (Technion Res & Dev Foundation); "Process for the Preparation of Corroles, Several such New Compounds Including Chiral Derivatives, and the Use Thereof”. Approved as US 6,541,628 B1, April 1 2003 and as European Patent No. EP1117666, December 1 2004 .

2.    D. Aviezer, A. Yayon, Z. Gross (Yeda Res & Dev and Technion Res & Dev Foundation); "Pharmaceutical Compositions Comprising Porphyrins and some Novel Porphyrin Derivatives", Priority date: November 8, 1999, International Publication Date: 18.5.2000 (WO 00/27379). Approved as US 6,730,666, May 4 2004.

3.    Z. Gross, A. Mahammed, I. Saltsman (Technion Res & Dev Foundation);  “Methods for the Preparation of Selectively-Substituted Corroles and New Substituted Corroles”. Approved as US 6,939,963 on September 6, 2005. European Patent Application No. 02743604.7.